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gnuwin II
GNU Generation http://gnugeneration.epfl.ch
http://gnuwin.epfl.ch/en
Windows
GPL
From Website:
"GNUWin II is a free software compilation for Windows. It includes numerous programs, completely free, which cover a wide spectrum of uses. The software included in GNUWin is not shareware nor freeware, but original free software and Open Source software, for which the source code is available, and that is and will always be free (free both as in "free speech", and as in "free beer"). Most programs included in this CD are also available for free and Open Source operating systems, such as GNU/Linux, BSD, etc. "

The complete application list on the website is impressive and the programs do not fit any more on a single CD. You can order either the CD compilation or go to the website and selectively download and install what you need. You will also find numerous articles that explain the free software and Open Source spirit.